Speical Physical Chemistry Seminar: Prospects for direct laser cooling of the LiRb molecule based on deperturbation analysis of Its A1Σ+ -b3Π complex and accompanying ab initio electronic calculations
Prof. Andrey Stolyarov, Head of the Laser Chemistry Department, Moscow State University
Zoom: https://tau-ac-il.zoom.us/j/86298492303
Abstract:
The work pursued the achievement of two main goals. Firstly, to provide a semi-empirical coupled-channel deperturbation model for describing the energetic properties in the singlet-triplet A-b complex of LiRb within experimental uncertainties, using two alternative procedures for solving the inverse spectroscopic problem. Secondly, to investigate the sensitivity of ab initio radiative probabilities predicted for spin-forbidden b3Π → X1Σ+ rovibronic transitions to the paricular deperturbation model accounting for regular spin-orbit interactions in the framework of "c" to "a" Hund’s case coupling transformation.
Seminar Organizer: Prof. Yoram Selzer
